The limits of precision monomer placement in chain growth polymerization
Identifieur interne : 001566 ( Main/Exploration ); précédent : 001565; suivant : 001567The limits of precision monomer placement in chain growth polymerization
Auteurs : Guillaume Gody [Royaume-Uni] ; Per B. Zetterlund [Australie] ; Sébastien Perrier [Royaume-Uni, Australie] ; Simon Harrisson [France]Source :
- Nature Communications [ 2041-1723 ] ; 2016.
Abstract
Precise control over the location of monomers in a polymer chain has been described as the ‘Holy Grail' of polymer synthesis. Controlled chain growth polymerization techniques have brought this goal closer, allowing the preparation of multiblock copolymers with ordered sequences of functional monomers. Such structures have promising applications ranging from medicine to materials engineering. Here we show, however, that the statistical nature of chain growth polymerization places strong limits on the control that can be obtained. We demonstrate that monomer locations are distributed according to surprisingly simple laws related to the Poisson or beta distributions. The degree of control is quantified in terms of the yield of the desired structure and the standard deviation of the appropriate distribution, allowing comparison between different synthetic techniques. This analysis establishes experimental requirements for the design of polymeric chains with controlled sequence of functionalities, which balance precise control of structure with simplicity of synthesis.
Url:
DOI: 10.1038/ncomms10514
PubMed: 26830125
PubMed Central: 4740409
Affiliations:
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Zetterlund</name><affiliation wicri:level="1"><nlm:aff id="a2"><institution>Centre for Advanced Macromolecular Design, School of Chemical Engineering, University of New South Wales</institution>, Sydney, New South Wales 2052,<country>Australia</country></nlm:aff><country xml:lang="fr">Australie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Perrier, Sebastien" sort="Perrier, Sebastien" uniqKey="Perrier S" first="Sébastien" last="Perrier">Sébastien Perrier</name><affiliation wicri:level="1"><nlm:aff id="a1"><institution>Department of Chemistry, University of Warwick</institution>, Warwick CV4 7AL,<country>UK</country></nlm:aff><country xml:lang="fr">Royaume-Uni</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation><affiliation wicri:level="1"><nlm:aff id="a3"><institution>Faculty of Pharmacy and Pharmaceutical Sciences, Monash University</institution>, Parkville, Victoria 3052,<country>Australia</country></nlm:aff><country xml:lang="fr">Australie</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author><author><name sortKey="Harrisson, Simon" sort="Harrisson, Simon" uniqKey="Harrisson S" first="Simon" last="Harrisson">Simon Harrisson</name><affiliation wicri:level="1"><nlm:aff id="a4"><institution>Laboratoire des Interactions Moléculaires et Réactivité Chimique et Photochimique, CNRS UMR5623, Université Paul Sabatier Toulouse III</institution>, 118 Route de Narbonne, Toulouse 31062,<country>France</country></nlm:aff><country xml:lang="fr">France</country><wicri:regionArea># see nlm:aff country strict</wicri:regionArea></affiliation></author></analytic><series><title level="j">Nature Communications</title><idno type="eISSN">2041-1723</idno><imprint><date when="2016">2016</date></imprint></series></biblStruct></sourceDesc></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en"><p>Precise control over the location of monomers in a polymer chain has been described as the ‘Holy Grail' of polymer synthesis. Controlled chain growth polymerization techniques have brought this goal closer, allowing the preparation of multiblock copolymers with ordered sequences of functional monomers. Such structures have promising applications ranging from medicine to materials engineering. Here we show, however, that the statistical nature of chain growth polymerization places strong limits on the control that can be obtained. We demonstrate that monomer locations are distributed according to surprisingly simple laws related to the Poisson or beta distributions. The degree of control is quantified in terms of the yield of the desired structure and the standard deviation of the appropriate distribution, allowing comparison between different synthetic techniques. This analysis establishes experimental requirements for the design of polymeric chains with controlled sequence of functionalities, which balance precise control of structure with simplicity of synthesis.</p></div></front><back><div1 type="bibliography"><listBibl><biblStruct><analytic><author><name sortKey="Lutz, J F" uniqKey="Lutz J">J.-F. Lutz</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Schmidt, B V K J" uniqKey="Schmidt B">B. V. K. J. Schmidt</name></author><author><name sortKey="Barner Kowollik, C" uniqKey="Barner Kowollik C">C. Barner-Kowollik</name></author></analytic></biblStruct><biblStruct><analytic><author><name sortKey="Lutz, J F" uniqKey="Lutz J">J.-F. Lutz</name></author><author><name sortKey="Ouchi, M" uniqKey="Ouchi M">M. Ouchi</name></author><author><name sortKey="Liu, D R" uniqKey="Liu D">D. R. Liu</name></author><author><name sortKey="Sawamoto, M" uniqKey="Sawamoto M">M. 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